This attack utilizes the frequent client-server roundtrips in Ajax conversation to scan a system. While Ajax does not open up new vulnerabilities per se, it does optimize them from an attacker point of view. In many XSS attacks the attacker must get a "hole in one" and successfully exploit the vulnerability on the victim side the first time, once the client is redirected the attacker has many chances to engage in follow on probes, but their is only one first chance. In a widely used web application this is not a major problem because 1 in a 1,000 is good enough in a widely used application.